Preparation
Synthesis of the Lewis Adduct of CuII with Imidazole; Stoichiometry of Reaction


Name:

Section:


Read

  1. The appropriate sections of your textbook.

Problems

  1. A Job's Method study was carried out for the reaction

    aA + bB ---> dD + fF

    Stock solutions of A and B containing 1 mmole per 10 mL of solution were prepared. These were used to prepare a series of 8 solutions containing varying amounts of A and B, but such that the total moles of A and B was maintained constant. The absorbance of each solution was then measured at a chosen wavelength (the same for all solutions), and the following data were obtained:

    Solutionvolume A solutionvolume B solutionA at chosen wavelength
    10.33.20.12
    20.43.1 0.16
    30.53.0 0.2
    40.72.8 0.28
    50.92.6 0.35
    61.22.3 0.31
    71.52.0 0.27
    81.81.7 0.23

    What is the stoichiometry of the reaction?