Preparation
Synthesis
of the Lewis Adduct of CuII with Imidazole; Stoichiometry
of Reaction
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Problems
Stock solutions of A and B containing 1 mmole per 10 mL of solution were prepared. These were used to prepare a series of 8 solutions containing varying amounts of A and B, but such that the total moles of A and B was maintained constant. The absorbance of each solution was then measured at a chosen wavelength (the same for all solutions), and the following data were obtained:
| Solution | volume A solution | volume B solution | A at chosen wavelength |
|---|---|---|---|
| 1 | 0.3 | 3.2 | 0.12 |
| 2 | 0.4 | 3.1 | 0.16 |
| 3 | 0.5 | 3.0 | 0.2 |
| 4 | 0.7 | 2.8 | 0.28 |
| 5 | 0.9 | 2.6 | 0.35 |
| 6 | 1.2 | 2.3 | 0.31 |
| 7 | 1.5 | 2.0 | 0.27 |
| 8 | 1.8 | 1.7 | 0.23 |
What is the stoichiometry of the reaction?